Electrochemical Patterning of Cu Current Collectors: An Enabler for Pure Silicon Anodes in High?Energy Lithium?Ion Batteries
نویسندگان
چکیده
Silicon (Si) is considered the most promising anode material for next-generation high-energy lithium-ion batteries. To enable use of pure Si anodes, patterning essential to reduce electrode degradation caused by volume changes during cycling. The authors herein report a facile and scalable Cu electrodeposition (Cu-ECD) process tailor topography current collectors directed formation columnar anodes physical vapor deposition (PVD). ECD parameters, such as concentration, temperature, potential, deposited amount Cu, are systematically varied. parameters applied modify commercial foils, which then used prepare via PVD. Modified resulting investigated scanning electron microscopy (SEM), laser confocal microscopy, adhesion tests. Selected characterized in battery cells regarding cycling stability. It shown that adjustment collector results significant increase SEM analysis revealed differences mechanical electrochemical capacity decay. Based on results, process–structure–property relationships between Cu-ECD collectors, their performance derived.
منابع مشابه
Electrochemical Performance of Porous Carbon/Tin Composite Anodes for SodiumIon and LithiumIon Batteries
The electrochemical performance of mesoporous carbon (C)/tin (Sn) anodes in Na-ion and Li-ion batteries is systematically investigated. The mesoporous C/Sn anodes in a Na-ion battery shows similar cycling stability but lower capacity and poorer rate capability than that in a Li-ion battery. The desodiation potentials of Sn anodes are approximately 0.21 V lower than delithiation potentials. The ...
متن کاملSix Thousand Electrochemical Cycles of Double-Walled Silicon Nanotube Anodes for Lithium Ion Batteries
متن کامل
Carbon NanotubeEnhanced Growth of Silicon Nanowires as an Anode for HighPerformance LithiumIon Batteries
Advanced lithium-ion batteries with high energy density, highrate capability, and excellent cycling performance are critically important for automotive and stationary energy storage applications such as electric vehicles, portable electronics, power tools, and energy storage for many types of renewable energy sources.[1–3] From the materials point of view, silicon is one of the most promising c...
متن کاملMetal Current Collector-Free Freestanding Silicon-Carbon 1D Nanocomposites for Ultralight Anodes in Lithium Ion Batteries
Although current collectors take up more weight than active materials in most lithium ion battery cells, so far research has been focused mainly on improving gravimetric capacities of active materials. To address this issue of improving gravimetric capacities based on overall cell components, we develop freestanding nanocomposites made of carbon nanofibers (CNFs) and silicon nanowires (SiNWs) a...
متن کاملLow-cost carbon-silicon nanocomposite anodes for lithium ion batteries
The specific energy of the existing lithium ion battery cells is limited because intercalation electrodes made of activated carbon (AC) materials have limited lithium ion storage capacities. Carbon nanotubes, graphene, and carbon nanofibers are the most sought alternatives to replace AC materials but their synthesis cost makes them highly prohibitive. Silicon has recently emerged as a strong ca...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Advanced Materials Interfaces
سال: 2022
ISSN: ['2196-7350']
DOI: https://doi.org/10.1002/admi.202200507